Enhancement of Corrosion Resistance and Electromagnetic Wave Absorption in Aluminium 6061 through Plasma Electrolytic Oxidation Coating with Ethylenediaminetetracetic Acid
DOI:
https://doi.org/10.23960/jemit.333Keywords:
Aluminium 6061, Corrosion resistance, Ethylenediaminetetraacetic acid, Electromagnetic absorber, Plasma electrolytic oxidationAbstract
Aluminium 6061 is well known for its good tensile strength and high corrosion resistance due to the natural protective oxide layer formed on its surface. However, the phenomenon of corrosion can still occur, particularly in aggressive environments, leading to material degradation. To further enhance corrosion resistance, a coating using the Plasma Electrolytic Oxidation (PEO) method with a concentrated solution of Na2SiO3, KOH, and EDTA was applied for 4 minutes. The addition of EDTA plays a crucial role not only in improving corrosion resistance but also in influencing the dielectric properties of the material, which subsequently affects the absorption of electromagnetic waves. Corrosion testing using the Tafel Polarization method revealed that the PEO coating with EDTA resulted in a more positive corrosion potential and a lower current density compared to untreated Aluminium 6061. Furthermore, EDTA enhances the porosity of the oxide layer, promoting the formation of micro-pores on the surface, which can trap corrosive agents and mitigate corrosion phenomena. Testing with a Vector Network Analyzer (VNA) at frequencies ranging from 8 GHz to 12 GHz demonstrated that the material exhibits an electromagnetic wave absorption of -1 dB. Overall, the application of PEO coating with EDTA significantly improves both corrosion resistance and electromagnetic wave absorption, making it suitable for various applications in the automotive, electronics, and energy industries.
Downloads
References
Davis, J. R. (Ed.). (1999). Corrosion of Aluminum and Aluminum Alloys. ASM International.
Dursun, T., & Soutis, C. (2014). Recent developments in advanced aircraft aluminum alloys. Materials & Design, 55, 404–413. https://doi.org/10.1016/j.matdes.2013.10.022
Guo, F., Cao, Y., Wang, K., et al. (2022). Effect of anodizing temperature on microstructure and tribological properties of 6061 aluminum alloy anodic oxide films. Coatings, 12(2), 314. https://doi.org/10.3390/coatings12020314
Hatch, J. E. (Ed.). (1984). Aluminum: Properties and Physical Metallurgy. ASM International.
Kagatikar, S. (2022). Gravimetric, electrochemical, and theoretical study on corrosion of AA6061/3 wt% SiC/3 wt% B4C hybrid composite in acid medium using EDTA. Academia.edu. https://www.academia.edu/105680398/Gravimetric_Electrochemical_and_Theoretical_Study_on_Corrosion_of_AA6061_3wt_SiC_3wt_B4C_Hybrid_Composite_in_Acid_Medium_Using_EDTA
Kamil, M. P., Al Zoubi, W., Yoon, D. K., Yang, H. W., & Ko, Y. G. (2020). Surface modulation of inorganic layer via soft plasma electrolysis for optimizing chemical stability and catalytic activity. Chemical Engineering Journal, 391. https://doi.org/10.1016/j.cej.2019.123614
Li, Y., et al. (2019). Plasma electrolytic oxidation of aluminum alloys: A review. Surface and Coatings Technology, 347, 1–12. https://doi.org/10.1016/j.surfcoat.2018.03.045
Liu, Y., et al. (2019). Effects of EDTA on the corrosion resistance of PEO coatings on aluminum alloys. Corrosion Science, 158, 108–116. https://doi.org/10.1016/j.corsci.2019.108116
Lucas, R., Mota, R., Abrahao, A., et al. (2022). Characterization of oxide coating grown by plasma electrolytic oxidation at different times on aluminum alloy AA2024-T3. MRS Communications, 12, 266–271. https://doi.org/10.1557/s43579-022-00131-3
Oh, G., Yoon, J., Huh, J., et al. (2023). Effect of frequency of plasma electrolytic oxidation on the microstructure and corrosion resistance of 6061 aluminium alloy. Surface and Coatings Technology, 471, 129861. https://doi.org/10.1016/j.surfcoat.2023.129861
Peng, Z., Xu, H., Liu, S., Qi, Y., & Liang, J. (2021). Wear and corrosion resistance of plasma electrolytic oxidation coatings on 6061 Al alloy in electrolytes with aluminate and phosphate. Materials, 14(14), 4037. https://www.mdpi.com/1996-1944/14/14/4037
Rogov, A., Nemcova, A., Hashimoto, T., et al. (2022). Analysis of electrical response, gas evolution, and coating morphology during transition to soft sparking PEO of Al. Surface and Coatings Technology, 442, 128142. https://doi.org/10.1016/j.surfcoat.2022.128142
Tu, C., Chen, X., Liu, C., & Li, D. (2023). Plasma electrolytic oxidation coatings of a 6061 Al alloy in an electrolyte with the addition of K2ZrF6. Materials, 16(11), 4142. https://www.mdpi.com/1996-1944/16/11/4142
Wang, Y., & Chen, Z. (2021). Impact of surface chemistry on impedance matching and electromagnetic wave absorption in PEO coatings for EMI shielding. IEEE Transactions on Electromagnetic Compatibility, 63(3), 1004–1012.
Yeshmanova, G., Blawert, C., Serdechnova, M., et al. (2024). Effect of electrolyte composition on the formation of PEO coatings on AA2024 aluminium alloy. Surface and Interfaces, 44, 103797. https://doi.org/10.1016/j.surfin.2024.103797
Zhang, Y., et al. (2018). Plasma electrolytic oxidation of aluminum alloys: A review. Surface and Coatings Technology, 347, 1–12. https://doi.org/10.1016/j.surfcoat.2018.03.045
Zhang, Y., et al. (2020). Effects of EDTA on the microstructure and properties of PEO coatings on aluminum alloys. Journal of Alloys and Compounds, 817, 152749. https://doi.org/10.1016/j.jallcom.2019.152749
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2025

This work is licensed under a Creative Commons Attribution 4.0 International License.







