FTIR, XRD, and SEM-EDX Characterization of Synthesized B-Type Carbonated Hydroxyapatite (CHAp) Based on Crab Shells

Authors

  • Muhamad Fajar Muarif Study program of physics, Universitas Islam Negeri Sultan Maulana Hasanuddin
  • Yusril Yusuf Departement of Physics, Universitas Gadjah Mada, Yogyakarta, Indonesia
  • Ade Irmadiki Agipa Study program of chemistry, Universitas Islam Negeri Sultan Maulana Hasanuddin, Banten, Indonesia

DOI:

https://doi.org/10.23960/jemit.v5i1.241

Keywords:

Type-B CHAp, Crab Shells, Precipitation

Abstract

The synthesis and characterization of B-type CHAp based on mangrove crab shells (Scylla serrata) as a source of calcium using the precipitation method has been successfully carried out. Based on the FTIR results, the substitution of carbonate ion for phosphate, which indicates the formation of B-type CHAp, is characterized by the appearance of absorption at wave numbers (CO32-) 1426 and 875 cm-1, PO43- at wave numbers 965, 619 & 569 cm-1. The XRD results show that diffraction peaks (211), (300), and (202) appear at an angle of 2θ ranging from 31°-34°, and there is a phenomenon of a-axis contraction and c-axis expansion in the HAp lattice structure. The SEM-EDX results show that the Ca/P ratio is 1.72, and the carbonate content is 5.01 wt%. All of these parameters are characteristics of CHAp, so it can be concluded that type-B CHAp has been formed.

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Published

2024-03-16

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Vol. 5 No. 1 (2024): Journal of Energy, Material, and Instrumentation Technology

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